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February 5, 2007 Carbon dioxide, a greenhouse gas that has become a bane of modern society, may have saved Earth from freezing over early in the planet's history, according to the first detailed laboratory analysis of the world's oldest sedimentary rocks. Scientists have theorized for years that high concentrations of greenhouse gases could have helped Earth avoid global freezing in its youth by allowing the atmosphere to retain more heat than it lost. Now a team from the University of Chicago and the University of Colorado at Boulder that analyzed ancient rocks from the eastern shore of Hudson Bay in northern Quebec, Canada, have discovered the first direct field evidence supporting this theory. The study shows carbon dioxide in Earth's atmosphere could have sustained surface temperatures above freezing before 3.75 billion years ago according to the researchers, led by The new study helps explain how Earth may have avoided becoming frozen solid early in its history, when astrophysicists believe the sun was 25 percent fainter than today. Previous studies had shown liquid water existed at Earth's surface even though the weak sun should have been unable to warm the planet above freezing conditions. But high concentrations of [CO2] or methane could have warmed the planet, according to the research team. The ancient rocks from "We now have direct evidence that Earth's atmosphere was loaded with [CO2] early in its history, which probably kept the planet from freezing and going the way of Mars," said Mojzsis. The [CO2] could even have played a role as a "planetary thermostat," since cold, icy conditions on Earth would have decreased the chemical weathering of rocks and increased the amount of [CO2] moving into the atmosphere, ratcheting up Earth's surface temperatures, according to Dauphas. In a companion article that appeared online Feb. 2 in Earth and Planetary Science Letters, Mojzsis, Cates and CU-Boulder undergraduate Jon Adam used a technique known as uranium-lead dating to establish the ancient age of the The CU-Boulder team analyzed the rocks by crushing them into powder and dating zircon crystals present in the rock, said Mojzsis. The technique allowed them to calculate the geologic age of the crystals based on the radioactive decay rate of the uranium and lead isotopes in relation to each other, a technique known to be accurate to 1 percent or less. "Zircon is nature's best timekeeper," said Mojzsis. "The tests show that the rocks in The landscape of the Hudson Bay region under study today, marked by hills of grassland and marsh peppered by lakes, streams and craggy outcroppings, is much different from the alien Earth of 3.8 billion years ago, said Mojzsis. In much earlier times, a dense atmosphere of [CO2] would have given the sky a reddish cast, and a greenish-blue ocean of iron-rich water would have lapped onto beaches, he said. While scientists have been concerned that the limited sample of Earth's oldest known rocks from West Greenland provided a biased view of early Earth, the
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